Determination of Reactivity Ratios for the System Methyl Methacrylate−n-Butyl Methacrylate
نویسندگان
چکیده
منابع مشابه
Microencapsulation of Butyl Palmitate in Polystyrene-co-Methyl Methacrylate Shell for Thermal Energy Storage Application
MicroEncapsulated Phase Change Materials (MEPCM) are green materials which could be used for thermal energy saving applications in buildings as a non-pollutant method for environmental. PCMs could passively reduce peak cooling loads in hot seasons because of their high energy storage capacities at a constant temperature. Purpose of this paper is manufacturing Microencapsulated PCM (MPCM) pr...
متن کاملSolubility and diffusivity of solvents and nonsolvents in poly(methyl methacrylate co butyl methacrylate)
In this study, thermodynamic properties, namely retention volume, infinitely dilute weight fraction activity coefficient, Flory–Huggins interaction parameter, solubility parameter of the polymer, partition coefficient and diffusion coefficients of the various solvents in poly(methyl methacrylate co butyl methacrylate) (PMMA co BMA) at infinite dilution of the solvent have been determined by inv...
متن کاملSynthesis of Ethylene Glycol Dimethacrylate-Methyl Methacrylate Copolymers, Determination of their Reactivity Ratios, and a Study of Dopant and Temperature Effects on their Conductivities
Ultraviolet radiation was used as a photochemical initiator to synthesize ethylene glycol dimethacrylate-methyl methacrylate copolymers. Infrared spectroscopy was used to calculate reactivity ratios and to identify the type of copolymerization. The reactivity ratios of EGDMA and MMA were calculated as 0.6993 and 1.8635, respectively. The effect of lithium perchlorate as a dopant on copolymer co...
متن کاملStatistical determination of chemical composition and monomer sequence distribution of poly(methyl methacrylate-co-tert-butyl methacrylate)s by multivariate analysis of 13C NMR spectra
To evaluate chemical compositions and heterogeneity of comonomer sequences in methyl methacrylate (MMA)-tert-butyl methacrylate (TBMA) copolymers, multivariate analysis was applied to the 13C nuclear magnetic resonance (NMR) spectra of the carbonyl, backbone quaternary and a-methyl carbons of the copolymers. A better linear relationship was found between the first principal component score and ...
متن کاملCalorimetric study of block-copolymers of poly(n-butyl acrylate) and gradient poly(n-butyl acrylate-co-methyl methacrylate)
The nanophase separation in diblock and triblock copolymers consisting of immiscible poly(n butyl acrylate) (block A) and gradient copolymers of methyl methacrylate (MMA) and n butyl acrylate (n BA) (block M/A) were investigated by means of their heat capacity, Cp, as a function of the composition of the blocks M/A and temperature. In all copolymers studied, both blocks are represented by their...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Macromolecules
سال: 1997
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma961377l